Lipase-mediated kinetic resolution of a synthetic equivalent of 2-hydroxymethylcyclopentadien-5-ol

Article Properties
Refrences
Title Journal Journal Categories Citations Publication Date
10.1016/S0040-4039(98)00833-8
10.1016/S0040-4039(00)84580-3
Reaction of enedione epoxides with base The Journal of Organic Chemistry
  • Science: Chemistry: Organic chemistry
  • Science: Chemistry: Analytical chemistry
  • Technology: Chemical technology: Polymers and polymer manufacture
  • Science: Chemistry
 36 1975
10.1016/0040-4039(96)00278-X
Spectral data of 8: IR (neat): ν=3407, 2963, 1730 cm−1. 1H NMR (CDCl3): δ=1.56 (1H, d, J=8.8 Hz), 1.65 (1H, d, J=8.8 Hz), 2.08 (3H, s), 2.64 (1H, m), 2.70 (1H, br s), 2.79 (2H, m), 3.70 (1H, d, J=10.7 Hz), 3.85 (1H, d, J=10.7 Hz), 5.52 (1H, d, J=10.2 Hz), 5.65 (1H, m), 5.92 (1H, m), 6.06 (1H, m). MS: m/z=220 (M+), 94 (100%), 66. Anal. calcd for C13H16O3 (M+): m/z=220.1099. Found: m/z=220.1089.